Dynamic assembly of a zinc-templated bifunctional organocatalyst in the presence of water for the asymmetric aldol reaction.
نویسندگان
چکیده
A bifunctional organocatalytic system consisting of simple pyridine ligands containing separate catalytic functionalities was assembled using ZnCl2. This novel metal-templated catalyst furnished high yields and stereoselectivities towards the aldol reaction. The addition of controlled amounts of water turned out to be crucial to dissolve the system and achieve optimal results.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 98 شماره
صفحات -
تاریخ انتشار 2015